Reinb Chemical

Знание

Material Safety Data Sheet: Bismuth Neodecanoate

1. Identification

Product Name: Bismuth Neodecanoate
Synonyms: Bismuth 2-Ethylhexanoate, Bismuth(III) neodecanoate
Chemical Formula: C40H74BiO8
CAS Number: 34364-26-6
Intended Use: Catalyst in polyurethane production, coatings, chemical synthesis
Manufacturer: Detail manufacturer’s information goes here, including address and telephone contacts
Emergency Phone Number: Local emergency services or company-specific hotline
Supplier Details: Name of supplier, address, phone number, and email for technical inquiries

2. Hazard Identification

Classification: Eye irritation Category 2, Skin sensitization Category 1, Acute toxicity (oral) Category 4
Signal Word: Warning
Hazard Statements: Harmful if swallowed, May cause eye irritation, May cause an allergic skin reaction
Pictograms: Exclamation mark
Precautionary Statements: Avoid contact with skin and eyes, Do not eat or drink while handling, Wash thoroughly after handling
Routes of Exposure: Inhalation, skin absorption, ingestion, eye contact
Potential Health Effects: Burning sensation in eyes, skin redness or rash, discomfort on ingestion, respiratory irritation on inhalation
Aggravated Medical Conditions: Existing skin disorders, respiratory problems, allergic conditions

3. Composition / Information on Ingredients

Chemical Name: Bismuth Neodecanoate
CAS Number: 34364-26-6
Concentration: ≥99% (by weight)
Impurities: Residual neodecanoic acid (trace), other bismuth carboxylates (trace)
Other Ingredients: None anticipated in commercial or technical grade samples

4. First Aid Measures

Inhalation: Move affected person to fresh air, offer respiratory support as needed, seek medical attention if symptoms persist such as dizziness or shortness of breath
Skin Contact: Remove contaminated clothing, wash skin with plenty of soap and water, seek medical attention if rash or persistent irritation develops
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, seek medical help if irritation intensifies or persists
Ingestion: Rinse mouth with water, do not induce vomiting, seek immediate medical advice for persistent discomfort or symptoms
Important Symptoms: Redness, burning, headache, nausea, possible sensitization reaction (delayed response possible)
Doctor’s Notes: Treat symptomatically, monitor for respiratory complications or allergic reactions

5. Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, CO2, foam, water spray (do not use high pressure jets that may spread contamination)
Specific Hazards: Combustion may produce carbon oxides and bismuth-containing fumes
Protective Equipment for Firefighters: Full protective clothing, self-contained breathing apparatus, chemical-resistant gloves
Special Procedures: Prevent runoff to drains, cool fire-exposed containers with water spray, remove containers from hazard zone if possible
Explosion Sensitivity: Not considered sensitive to static discharge or mechanical impact

6. Accidental Release Measures

Personal Precautions: Use appropriate protective gear including gloves, goggles, and breathing protection if dust or vapor forms
Environmental Precautions: Prevent release into sewers, surface water, or soil, contain spillage using impervious material or absorbent
Cleanup Methods: Absorb spill using inert materials (sand, earth), collect in suitable containers for disposal, ventilate area, wash area with large amounts of water
Decontamination: Use mild detergent solutions for residue, avoid solvent-based cleaners unless specified by manufacturer
Disposal: Dispose according to hazardous waste regulations and local guidelines
Reporting Requirements: Notify appropriate regulatory authorities if release results in environmental contamination above permissible threshold

7. Handling and Storage

Precautions for Safe Handling: Ensure good ventilation or exhaust at workplace, wear suitable protective clothing, avoid formation of dust or vapors, handle with care to prevent spills
Advice on General Occupational Hygiene: Wash hands and face after handling, do not eat, drink, or smoke in work areas, regularly clean and inspect PPE
Conditions for Safe Storage: Store in a tightly sealed original container, in a cool, dry place away from direct sunlight and sources of ignition, segregate from acids and oxidizers
Storage Temperature: Maintain between 5°C and 30°C for optimal stability
Incompatible Materials: Strong acids, alkaline substances, oxidizing agents
Packaging Materials: High-density polyethylene (HDPE) or inert glass recommended for long-term storage

8. Exposure Controls and Personal Protection

Exposure Limits: No specific occupational exposure limits established by OSHA, NIOSH, or ACGIH
Engineering Controls: Provide local exhaust ventilation, process enclosure, or dust extraction as needed
Personal Protective Equipment: Chemical-resistant gloves (nitrile, neoprene), safety goggles or face shield, suitable chemical-resistant clothing or apron
Respiratory Protection: Use a NIOSH-approved respirator if ventilation is inadequate or if exposure limits are exceeded
Environmental Controls: Prevent discharge to the environment, monitor and contain any accidental releases, regularly test air concentrations in high-exposure workplaces

9. Physical and Chemical Properties

Appearance: Clear, pale yellow to orange liquid
Odor: Mild, characteristic organic odor
pH: Not applicable (non-aqueous)
Density: 1.15–1.25 g/cm3 at 20°C
Boiling Point: Decomposes before boiling
Melting Point: Not applicable (liquid at ambient conditions)
Flash Point: >100°C (closed cup)
Solubility: Insoluble in water, soluble in organic solvents (such as toluene and xylene)
Vapor Pressure: Low at 20°C
Viscosity: 150–400 mPa·s at 25°C
Partition Coefficient (log Kow): Not determined
Auto-ignition Temperature: Not self-igniting
Explosive Properties: Not explosive under normal conditions

10. Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling conditions
Possibility of Hazardous Reactions: May react with strong acids and oxidizers, risk of violent reaction with incompatible substances
Conditions to Avoid: Heat, moisture, strong light, open flames
Incompatible Materials: Strong acids, strong bases, oxidizing agents
Hazardous Decomposition Products: Thermal decomposition can produce bismuth oxides, carbon oxides, and irritating organic fumes

11. Toxicological Information

Acute Toxicity: Oral LD50 (rat): 1000–2000 mg/kg (estimated)
Skin Contact: Moderate irritation and possible sensitization reaction
Eye Contact: Irritation and redness, may cause blurred vision if not rinsed promptly
Inhalation: May cause respiratory tract irritation, coughing, shortness of breath with prolonged or repeated exposure
Chronic Effects: Long-term exposure may aggravate pre-existing skin or respiratory conditions, reports of possible allergic contact dermatitis
Sensitization: Sensitizing to skin in some individuals
Mutagenicity/Carcinogenicity: Not classified as mutagenic, carcinogenic, or genotoxic by major agencies
Reproductive Effects: No adverse reproductive or teratogenic effects have been documented in available studies
Target Organs: Skin, eyes, respiratory system
Symptoms of Overexposure: Nausea, headache, fatigue, skin irritation, respiratory discomfort

12. Ecological Information

Aquatic Toxicity: May cause short-term toxicity to aquatic organisms (daphnia and fish studies indicate moderate toxicity)
Persistence and Degradability: Bismuth complexes show slow degradation in soil and water, organic ligands may persist in low-oxygen environments
Bioaccumulative Potential: Bismuth does not bioaccumulate appreciably, neodecanoate moiety may partition to sediments
Mobility in Soil: Limited mobility, may adsorb to soil particles
Other Adverse Effects: Avoid uncontrolled release into the environment; local wastewater regulations apply
Regulatory Information: Not listed as a marine pollutant, no Ozone Depleting Substances, monitored under regional chemical safety programs

13. Disposal Considerations

Waste Treatment Methods: Collect and store for proper disposal by licensed hazardous waste contractor
Contaminated Packaging: Rinse containers thoroughly, dispose of as hazardous waste per local regulations, do not reuse containers for other chemicals
Disposal Precautions: Do not discharge to drains or waterways, incinerate at authorized facility if permissible
Regulatory Disposal Requirements: Comply with national and local hazardous waste disposal legislation, contact local waste authority for guidance

14. Transport Information

UN Number: Not classified as dangerous goods for transport under ADR, RID, IMDG, IATA
Proper Shipping Name: Bismuth Neodecanoate, non-hazardous for transport
Transport Hazard Class: Not regulated
Packing Group: Not assigned
Environmental Hazards: Not a marine pollutant
Transport Precautions: Avoid spillage in transit, store upright, keep containers sealed, secure against overturning and impact

15. Regulatory Information

Inventory Status: Listed or notified under TSCA (USA), REACH (EU), DSL (Canada), AICS (Australia), ENCS (Japan)
Safety, Health, and Environmental Regulations: No specific restrictions, comply with workplace chemical legislation
Label Requirements: As per GHS hazardous substance guidelines
Additional National Requirements: Country-specific workplace exposure and environmental release provisions apply, consult relevant health and safety agencies
Chemical Safety Assessment: Chemical safety report available on request for workplace risk management